You can use pd.Series.str.extract
:
print (df["Test"].str.extract("([^\s]*)\s?(1.*)"))
0 1
0 1 RTWXA LC WTHML
1 2TE7 1 RHRRA LY HGHRL
2 1 WJKFD LF LPKRF
3 ATEGR/5 1 WJFTA LC TRGEH
4 1 POKJD LD PLERT
5 4ARF/3 1 EDFRT TG IUYHT
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